赵英博课题组介绍
赵英博,助理教授、研究员、独立课题组长 电子邮件:zhaoyb2@shanghaitech.edu.cn 实验室:bat365中文官方网站2号楼509 教育及研究经历 2008-2012, 中国科学技术大学少年班学院,化学专业,学士学位 2012-2017, 加州大学伯克利分校化学系,博士学位 (导师:Omar Yaghi 院士) 2017-2021, 加州大学伯克利分校电子工程系,博士后研究员(合作导师:Ali Javey教授) 2021年8月- bat365中文官方网站助理教授,研究员 |
研究方向
课题组研究方向包括框架材料(MOF&COF)的合成、物性研究及其在固态电池等离子型器件中的应用。目前的主要研究方向是玻璃态MOF和COF的新概念设计。
框架材料
设计可用于离子传输和气体分离的玻璃态金属有机框架,以及具有响应性的共价有机框架,并分别应用于固态电解质、离子和气体分离以及分子传感。
金属与共价有机框架材料
储能和传感器件
基于具有离子传输和客体响应特性的分子框架结构,发展基于新型固态电解质的储能器件和可用于环境健康监测的生物小分子传感器件。
适用于新型分子材料的器件结构
2024年计划与上海光源联合招收一名研究生开展谱学和全散射研究
2024 Wei, L#., Hai, X#., Xu, T., Wang, Z., Jiang, W., Jiang, S., Wang, Q., Zhang, Y.-B*., Zhao, Y*; Encoding ordered structural complexity to covalent organic frameworks. Nat. Commun. 15 (1), 2411 Qi, A., Li, C., Evans, J., Zhao, Y*., Li, Tao*; Self-sorting of Interfacial Compatibility in MOF-based Mixed Matrix Membranes. Angew. Chem. Int. Ed.,e202400474. Huang, Y., Qi, A., Li, S., Tang, Lu., Zhao, Y*., Li, Tao*; Rapid coating of polyamide, polyurea, and polythiourea on metal–organic framework surfaces. APL Mater. 12, 031116 (2024) 2023 Zhang, Y.,# Liu, Y.,# Bao, W., Zhang, X., Yan, P., Yao, X., Chen, M.-Z., Xie, T-Y., Cao, L., Cai, X., Li, H., Deng, Y., Zhao, L., Zeng, M-H., Jiang, S., Zhao, Y.,* Xie, J.*; Monolithic Titanium Alkoxide Networks for Lithium-Ion Conductive All-Solid-State Electrolytes. Nano Lett. 2023, 23, 4066–4073. Chen, M.-Z., Li, J., Liao, S., Guo, Y. -H., Liu, T., Ma, R. -F., Xie, T. -Y., Liu, W. -D., Peng, S. -X., Kuang, X., Yin, Z.,* Zhao, Y.,* Zeng, M.-H.,*; Multi-stage Transformations of a Cluster-Based Metal-Organic Framework: Perturbing Crystals to Glass-Forming Liquids that Re-Crystallize at High Temperature. Angew. Chem. Int. Ed, e202305942. Yin, Z.,* Zhao, Y.,* Zeng, M.-H.,* Challenge, Advance and Emerging Opportunities for Metal-Organic Framework Glasses: from Dynamic Chemistry to Material Science and Noncrystalline Physics. Acta Chimica Sinica, 2023, 81, 246-252. Bao, W.; Zhang, Y.; Cao, L.; Jiang, Y.; Zhang, H.; Zhang, N.; Liu, Y.; Yan, P.; Wang, X.; Liu, Y.; Li, H.; Zhao, Y.; Xie, J.*; A H2O-initiated crosslinking strategy for ultrafine nanoclusters reinforced high toughness polymer-in-plasticizer solid electrolyte Adv. Mater. 2023, 2304712. https://doi.org/10.1002/adma.202304712 Xu, Y.; Sun, T.; Zeng, T.; Zhang, X.; Yao, X.; Liu, S.; Shi, Z.; Wen, W.; Zhao, Y.; Jiang, S.; Ma, Y.; Zhang, Y.-B.*; Symmetry-breaking dynamics in a tautomeric 3D covalent organic framework. Nat. Commun. 2023, 14, 4215. Zhang, X.; Xu, Z.; Wang, Z.; Liu, H.; Zhao, Y.; Jiang, S.*; High-throughput and machine learning approaches for the discovery of metal organic frameworks. APL Materials, 2023, 11, 060901, 8 pp. Liu, T.; Fu, Q.; Li, Y.; Han, X.; Wang, S.; Taniguchi, T.; Watanabe, K.; Wan, D.; Zhang, Q.; Zhao, Y.; Ni, Z.; Ding, F.; Hu, Z,; Yuan, X.*; Lu, J.*; Silver nanoparticle-induced enhancement of light extraction in two-dimensional light-emitting diodes. Optics Letters, 2023, 48, 4372-5. 2022 Yin, Z.,; Zhao, Y.,; Wan, S.,; Yang, J.,; Shi, Z.,; Peng, S.-X.,; Chen, M.-Z.,; Xie, T.-Y.,; Zeng, T.-W.,; Yamamuro, O.,; Nirei, M.,; Akiba, H.,; Zhang, Y.-B.,*; Yu, H.-B.,*; Zeng, M.-H.,*; Synergistic Stimulation of Metal–Organic Frameworks for Stable Super-cooled Liquid and Quenched Glass, J. Am. Chem. Soc. 2022, 144 (29), 13021-13025. Wei, L#., Sun, T#., Shi, Z. Xu, Z., Wen, W., Jiang, S., Zhao, Y*., Ma, Y*., Zhang, Y.-B*.; Guest-adaptive molecular sensing in a dynamic 3D covalent organic framework. Nat Commun 2022, 13, 7936. https://doi.org/10.1038/s41467-022-35674-8 Selected Publications Before ShanhaiTech 分子框架材料新结构 Liu, Y#., Ma, Y#., Zhao, Y#., Sun, X., Gándara, F., Furukawa, H., Liu, Z., Zhu, H., Zhu, C., Suenaga, K., Oleynikov, P., Alshammari, A. S., Zhang, X., Terasaki, O.* & Yaghi, O. M.*; Weaving of Organic Threads into a Crystalline Covalent Organic Framework. Science 351, 365-369, (2016).
Zhao, Y., Lee, S-Y., Becknell, N., Yaghi, O. M.*, & Angell, C.A.*; Nanoporous Transparent MOF Glasses with Accessible Internal Surface. J. Am. Chem. Soc.138, 10818-10821, (2016).
Zhao, Y#., Guo, L#., Gándara, F., Ma, Y., Liu, Z., Zhu, C., Lyu, H., Trickett, C., Kapustin, E., Terasaki, O., Yaghi, O. M.*; A Synthetic Route for Crystals of Woven Structures, Monodisperse Nanocrystals, and Thin Films of Covalent Organic Frameworks. J. Am. Chem. Soc. 139, 13166–13172, (2017). Jiang, J#., Zhao, Y.#., & Yaghi, O. M.*; Covalent Chemistry beyond Molecules. J. Am. Chem. Soc. 138, 3255-3265, (2016).
分子框架的界面控制与功能 Zhao, Y#., Kornienko, N.#, Liu, Z., Zhu, C., Asahina, S., Kuo, T.-R., Bao, W., Xie, C., Hexemer, A., Terasaki, O., Yang, P.* & Yaghi, O. M.*; Mesoscopic Constructs of Ordered and Oriented Metal-organic Frameworks on Plasmonic Silver Nanocrystals. J. Am. Chem. Soc. 137, 2199-2202, (2015).
Kornienko, N.#, Zhao, Y.#, Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M.* & Yang, P.*; Metal-organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide. J. Am. Chem. Soc. 137, 14129-14135, (2015). Zhao, H.#, Zhao, Y.#, Song, Y., Zhou, M., Lv, W., Tao, L., Feng, Y., Song, B., Ma, Y., Zhang, J., Xiao, J., Wang, Y., Lien, D.-H., Amani, M., Kim, H., Chen, X., Wu, Z., Ni, Z., Wang P., Shi, Y., Ma, H.*, Zhang, X., Xu, J.-B., Troisi, A., Javey, A.*, Wang, X.*; Strong optical response and light emission from a monolayer molecular crystal. Nat. Commun., 10, 1-9, (2019).
Zhao, Y., Wang, V., Javey, A.*; Molecular materials with short radiative lifetime for high-speed light-emitting devices. Matter, 3, 1832-1844,(2020). 功能器件设计与构筑 Zhao, Y.#, Wang, V.#, Lien, D.-H.#, Javey, A.*; Generic electroluminescent device for emission from infrared to ultraviolet wavelengths. Nat. Electron.,3, 612–621,(2020). Wang, V., Zhao, Y., Javey, A.*; Performance limits of an alternating current electroluminescent device. Adv. Mater., 33, 2005635, (2021). Nyein, H.Y.Y.#, Bariya, M.#, Kivimäki, L., Uusitalo, S., Liaw, T. S., Jansson, E., Ahn, C. H., Hangasky, J.A., Zhao, J., Lin, Y., Happonen, T., Chao, M., Liedert, C., Zhao, Y., Tai, L.-C., Hiltunen, J., Javey, A.*; Regional and correlative sweat analysis using high-throughput microfluidic sensing patches toward decoding sweat. Sci. Adv., 5, eaaw9906, (2019). Ji, W., Zhao, Y., Fahad, H.M., Bullock, J., Allen, T., Lien, D.-H., Wolf, S.D., Javey, A.*; Dip coating passivation of crystalline silicon by lewis acids. ACS nano, 13, 3723-3729, (2019). Bariya, M.#, Shahpar, Z.#, Park, H., Sun, J., Jung, Y., Gao, W., Nyein, H.Y.Y., Liaw, T. S., Tai, L.-C., Ngo, Q. P., Chao, M., Zhao, Y., Hettick, M., Cho, G.*, Javey, A.*; Roll-to-Roll gravure printed electrochemical sensors for wearable and medical devices. ACS nano, 12, 6978-6987, (2018). Other Publications Before ShanhaiTech Kim, H.#, Ahn, G.H.#, Cho, J., Amani, M., Mastandrea, J. P., Groschner, C. K., Lien, D.-H., Zhao, Y., Ager, J. W., Scott, M.C., Chrzan, D. C., Javey, A.*; Synthetic WSe2 monolayers with high photoluminescence quantum yield. Sci. Adv., 5, eaau4728, (2019). Zhao, P., Wang, R., Lien, D.-H., Zhao, Y., Kim, H., Cho, J., Ahn, G. H., Javey, A.*; Scanning probe lithography patterning of monolayer semiconductors and application in quantifying edge recombination. Adv. Mater., 31, 1900136, (2019). Diercks, C. S.#, Lin, S.#, Kornienko, N., Kapustin, E. A., Nichols, E. M., Zhu, C., Zhao, Y., Chang, C. J.*, & Yaghi, O. M.*; Reticular electronic tuning of porphyrin active sites in covalent organic frameworks for electrocatalytic carbon dioxide reduction. J. Am. Chem. Soc. 140, 1116-1122, (2018). Rungtaweevoranit, B.*, Zhao, Y.*, Choi, K. M. & Yaghi, O. M.*; Cooperative Effects at the Interface of Nanocrystalline Metal-organic Frameworks. Nano Res. 9, 47-58, (2016). Lin, S.#, Diercks, C. S.#, Zhang, Y.-B.#, Kornienko, N., Nichols, E. M., Zhao, Y., Paris, A. R., Kim, D., Yang, P., Yaghi, O. M. * & Chang, C. J.*; Covalent Organic Frameworks Comprising Cobalt Porphyrins for Catalytic CO2 Reduction in Water. Science 349, 1208-1213, (2015). Peri, D., Ciston, J., Gándara, F., Zhao, Y., Yaghi, O. M.*; Crystalline Fibers of Metal–Peptide Double Ladders. Inorg. Chem. 52, 13818-13820, (2013).
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助理研究员
魏蕾 weilei1@shanghaitech.edu.cn
博士后
刘杉 liushan1@shanghaitech.edu.cn
2021级硕士
刘盈, liuying3@shanghaitech.edu.cn
海馨月, haixy@shanghaitech.edu.cn
张紫惠, zhangzh2@shanghaitech.edu.cn
2022级硕士
刘辰宇,liuchy2022@shanghaitech.edu.cn
戚乘航,qichh2022@shanghaitech.edu.cn
覃美华,qinmh2022@shanghaitech.edu.cn
2023级硕士
邓艳欣,dengyx2023@shanghaitech.edu.cn
本科生
孔涵哲(2022级)
刘雨菲(2022级)
毕业成员
郑江楠(2018级本科生,现为中国科学院硕士生)
陈明珠(广西师大2020级硕士,访问生)
谢天怡(广西师大2020级硕士,访问生)